Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based
semi-interpenetrating hydrogels

ZIAEE, Farshid; MIRTALEB, Fakhrosadat; AZAR, Amir SEPEHRIAN; jozaghkar, mohammad reza

doi:10.3906/kim-2109-50

Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels

Mohammad Reza JOZAGHKAR, (Department of Polymer Science, Iran Polymer and Petrochemical Institute, Tehran, Iran)

Amir SEPEHRIAN AZAR, (Department of Chemistry, Ahar Branch, Islamic Azad University, Ahar, Iran)

Farshid ZIAEE, (Department of Polymer Science, Iran Polymer and Petrochemical Institute, Tehran, Iran)

Fakhrosadat MIRTALEB (Department of Polymer Science, Iran Polymer and Petrochemical Institute, Tehran, Iran)

Turkish Journal of Chemistry

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Yıl: 2022 Cilt: 46 Sayı: 2 Sayfa Aralığı: 499 - 505 Metin Dili: İngilizce DOI: 10.3906/kim-2109-50 İndeks Tarihi: 05-07-2022

Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels

Öz:

The aim of this study was to synthesize amphiphilic semi-IPN hydrogels based on acrylic acid (AA) and chitosan (CS) using AIBN as an initiator and N,N’methylene bis acrylamide as a crosslinking agent. The swelling behavior of the hydrogels was evaluated at a variety of pH values, temperature, the salinity of media and time, and the swelling mechanism was investigated using Fickian diffusion and Schott’s 2nd-order-kinetics models. FTIR spectroscopy was used to confirm the synthesis of AA/CS hydrogel. The swelling results showed that, in the acidic media, as the CS content increase the hydrogel swelling ratio reduces. It was found that the maximum swelling ratio (8550%) is attained for the sample HAC2 with an AA/CS ratio of 1:0.001 in the alkaline Ph value. It also revealed that the absorption capacity is directly dependent on the temperature and inversely related to the salt concentration. Besides, the absorption capacity of the synthesized hydrogels in the saline solution of $Na_2 SO_4$ was higher than NaCl.

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Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	jozaghkar m, AZAR A, ZIAEE F, MIRTALEB F (2022). Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. , 499 - 505. 10.3906/kim-2109-50
Chicago	jozaghkar mohammad reza,AZAR Amir SEPEHRIAN,ZIAEE Farshid,MIRTALEB Fakhrosadat Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. (2022): 499 - 505. 10.3906/kim-2109-50
MLA	jozaghkar mohammad reza,AZAR Amir SEPEHRIAN,ZIAEE Farshid,MIRTALEB Fakhrosadat Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. , 2022, ss.499 - 505. 10.3906/kim-2109-50
AMA	jozaghkar m,AZAR A,ZIAEE F,MIRTALEB F Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. . 2022; 499 - 505. 10.3906/kim-2109-50
Vancouver	jozaghkar m,AZAR A,ZIAEE F,MIRTALEB F Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. . 2022; 499 - 505. 10.3906/kim-2109-50
IEEE	jozaghkar m,AZAR A,ZIAEE F,MIRTALEB F "Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels." , ss.499 - 505, 2022. 10.3906/kim-2109-50
ISNAD	jozaghkar, mohammad reza vd. "Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels". (2022), 499-505. https://doi.org/10.3906/kim-2109-50

APA	jozaghkar m, AZAR A, ZIAEE F, MIRTALEB F (2022). Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. Turkish Journal of Chemistry, 46(2), 499 - 505. 10.3906/kim-2109-50
Chicago	jozaghkar mohammad reza,AZAR Amir SEPEHRIAN,ZIAEE Farshid,MIRTALEB Fakhrosadat Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. Turkish Journal of Chemistry 46, no.2 (2022): 499 - 505. 10.3906/kim-2109-50
MLA	jozaghkar mohammad reza,AZAR Amir SEPEHRIAN,ZIAEE Farshid,MIRTALEB Fakhrosadat Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. Turkish Journal of Chemistry, vol.46, no.2, 2022, ss.499 - 505. 10.3906/kim-2109-50
AMA	jozaghkar m,AZAR A,ZIAEE F,MIRTALEB F Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. Turkish Journal of Chemistry. 2022; 46(2): 499 - 505. 10.3906/kim-2109-50
Vancouver	jozaghkar m,AZAR A,ZIAEE F,MIRTALEB F Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels. Turkish Journal of Chemistry. 2022; 46(2): 499 - 505. 10.3906/kim-2109-50
IEEE	jozaghkar m,AZAR A,ZIAEE F,MIRTALEB F "Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels." Turkish Journal of Chemistry, 46, ss.499 - 505, 2022. 10.3906/kim-2109-50
ISNAD	jozaghkar, mohammad reza vd. "Preparation, assessment, and swelling study of amphiphilic acrylic acid/chitosan-based semi-interpenetrating hydrogels". Turkish Journal of Chemistry 46/2 (2022), 499-505. https://doi.org/10.3906/kim-2109-50