Yıl: 2022 Cilt: 10 Sayı: 2 Sayfa Aralığı: 216 - 229 Metin Dili: İngilizce DOI: 10.29109/gujsc.1091233 İndeks Tarihi: 29-07-2022

An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass

Öz:
This study applied heat treatment to the CMAS parent glass produced using brucite with calcite, kaolin, ulexite natural raw materials, and commercial MgF2, considering the DTA measurements. The crystallization behaviour and the growth directions of the crystals were investigated. XRD analyses and SEM investigations revealed that the anorthite crystals were formed during heat treatment, and glass-ceramic was obtained in the CAS system by surface crystallization. According to EBSD measurements, the {100} faces of the some anorthite crystals just below the surface have a relatively higher ratio of lying parallel to the surface than their edges ({110}) and corners ({111}). These crystals grew by orienting in the same direction to the inner region of the remaining glass. However, many crystals exhibited random orientation. The tendency of crystals' same planes to lie parallel to the surface was slightly less in the inner regions than those on the surface.
Anahtar Kelime: Glass ceramics EBSD Anorthite Surface Crystallization

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • [1] Deubener, J., Allix, M., Davis, M.J., Duran, A., Höche, T., Honma, T., Komatsu, T., Krüger, S., Mitra, I., Müller, R., Nakane, S., Pascual, M.J., Schmelzer, J.W.P., Zanotto, E.D., Zhou, S. (2018). Updated definition of glass-ceramics. Journal of Non-Crystalline Solids, 501, 3–10. https://doi.org/10.1016/j.jnoncrysol.2018.01.033.
  • [2] Sakamoto, A., Yamamoto, S. (2010). Glass–Ceramics: Engineering Principles and Applications. International Journal of Applied Glass Science, 1(3), 237–247. https://doi.org/10.1111/j.2041- 1294.2010.00027.x.
  • [3] Mcmillan, P.W. (1982). The Crystallisation of Glasses. Journal of Non-Crystalline Solids, 52, 67-76. https://doi.org/10.1016/0022-3093(82)90281-2.
  • [4] Zanotto, E.D. (2000). Experimental studies of surface nucleation and crystallization of glasses. in Nucleation and Crystallization in Glass and Liquids. Journal of American Ceramic Society, 65-74. ISBN-13: 978-0944904572.
  • [5] Davis, M.J., Zanotto, E.D. (2017). Glass-ceramics and realization of the unobtainable: Property combinations that push the envelope. Materials Research Society, 42, 195-199. https://doi.org/10.1557/mrs.2017.27.
  • [6] Fernandes, M.H.V., Silva, A.M.B. (2016). Glass-Ceramics: Concepts and Practical Aspects. in Overall Aspects of Non-Traditional Glasses: Synthesis, Properties and Applications. Bentham ebooks, 39-65. ISBN: 978-1-68108-208-0.
  • [7] Ozabaci, M., Aksan, M.A., Kirat, G., Kizilaslan, O., Yakinci, M.E. (2006). Preparation and characterization of CaO-Al2O3-SiO2 (CAS) glass-ceramics. Journal of Non-Crystalline Solids, 454, 8–12. https://doi.org/10.1016/j.jnoncrysol.2016.10.019.
  • [8] Morsi, M.M., Khater, G.A., Range, K.J. (2001). Glass ceramics in the system diopside, anorthiteorthoclase prepared by using some industrial waste materials. Glass Technology, 42(6), 160-164.
  • [9] Pinckney, L.R. (2001). Glass Ceramics, Encyclopedia of Materials: Science and Technology. Elsevier, 3535-3540. https://doi.org/10.1016/B0-08-043152-6/00629-X.
  • [10] Marghussian, V. (2015). Nanoglass Ceramics Processing Properties and Applications. Elsevier, 2- 61.
  • [11] Leonelli, C., Manfredini, T., Paganelli, M., Pozzi, P., Pellacani, G.C. (1991). Crystallization of some anorthite-diopside glass precursors. Journal of Materials Science, 26, 5041-5046.
  • [12] Carter, C.B., Norton, M.G. (2013). Processing Glass and Glass-Ceramics in Ceramic Materials Science and Engineering. Springer, New York, 389-409. https://doi.org/10.1007/978-0-387-46271- 4_26
  • [13] Xiao, H., Cheng, Y., Yang, Q., Senda, T. (2006). Mechanical and tribological properties of calcia– magnesia–alumina–silica-based glass–ceramics prepared by in situ crystallization. Materials Science and Engineering:A, 423(1–2),170-174. https://doi.org/10.1016/j.msea.2005.09.131.
  • [14] Merkit, Z.Y., Toplan, H.O., Toplan, N. (2018). The crystallization kinetics of CaO–Al2O3–SiO2 (CAS) glass–ceramics system produced from pumice and marble dust. Journal of Thermal Analysis and Calorimetry, 134, 807–811. https://hdl.handle.net/20.500.12619/69704.
  • [15] Russel, C., Wisniewski, W. (2021). How Can Surface-Crystallized Glass-Ceramics Be Piezoelectric?. Crystal Growth Design, 21, 2405−2415. https://doi.org/10.1021/acs.cgd.1c00029.
  • [16] Wisniewski, W., Russel, C. (2015). EBSD measurements of phlogopite glass ceramics. The Royal Society of Chemistry, 17, 8671–8675. https://doi.org/10.1039/c5ce01763g.
  • [17] Wisniewski, W., Nagel, M., Volksch, G., Russel, C. (2010). Electron Backscatter Diffraction of Fresnoite Crystals Grown from the Surface of a 2BaO3 TiO2 2.75SiO2 Glass. Crystal Growth Design, 10(3), 1414-1418. https://doi.org/10.1021/cg901407d.
  • [18] Russel, C. (1997). Oriented crystallization of glass. A review. Journal of Non-Crystalline Solids, 219, 212-218. https://doi.org/10.1016/S0022-3093(97)00271-8.
  • [19] Muller, R., Zanotto, E.D., Fokin, V.M. (2000). Surface crystallization of silicate glasses: nucleation sites and kinetics. Journal of Non-Crystalline Solids, 274, 208−231. https://doi.org/10.1016/S0022- 3093(00)00214-3.
  • [20] Peruzzo, L., Fenzi, F., Vigato, P.A. (2011.) Electron Backscatter Diffraction (EBSD): A New Technique for the Identification of Pigments and Raw Materials in Historic Glasses and Ceramics. Archaeometry, 53(1), 178–193. https://doi.org/10.1111/j.1475-4754.2010.00540.x.
  • [21] Stojakovic, D. (2012). Electron backscatter diffraction in materials characterization. Processing and Application of Ceramics, 6(1), 1–13. https://doi.org/10.2298/PAC1201001S.
  • [22] Schwartz, A.J., Kumar, M., Adams, B.L., Field, D.P. (2009). Electron backscatter diffraction in materials science. 2nd edition, Springer, New York. ISBN: 978-0-387-88136-2.
  • [23] See http://www.ebsd.com/introduction for further details.
  • [24] Stebbins, J.F., Dubinsky, E.V., Kanehashi, K., Kelsey, K.E. (2008). Temperature effects on nonbridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts. Geochimica et Cosmochimica Acta, 72, 910–925. https://doi.org/10.1016/j.gca.2007.11.018.
  • [25] Yurdakul, A., Günkaya, G., Kavas, T., Dölekçekiç, E., Karasu, B. (2014). Investigations on Fiber Production Attempts from the Borosilicate and SMFMZS (SrO-MgO-Fe2O3-Mn2O3-ZrO2-SiO2) Glass Systems. Afyon Kocatepe Üniversitesi Fen ve Mühendislik Bilimleri Dergisi, 14(OZ5701), 1-9.
  • [26] Fox, K.M., Edwards, T.B., Peeler, D.K. (2008). Control of Nepheline Crystallization in Nuclear Waste Glass. International Journal of Applied Ceramic Technology, 5(6), 666–673. https://doi.org/10.1111/j.1744-7402.2008.02250.x.
  • [27] Deshkar, A., Gulbiten, O., Youngman, R.E., Mauroc, J.C., Goel, A. (2020). Why does B2O3 suppress nepheline (NaAlSiO4) crystallization in sodium aluminosilicate glasses? Physical Chemistry Chemical Physics, https://doi.org/10.1039/D0CP00172D.
  • [28] Sitzman, S.D., Nolze, G., Nowell, M.M. (2010). EBSD Pattern Quality and its Use in Evaluating Sample Surface Condition. Microscopy and Microanalysis, 16, 698-699. https://doi.org/10.1017/S143192761005467X.
  • [29] Wright, S.I., Nowell, M.M. (2006). EBSD Image Quality Mapping. Microscopy and Microanalysis, 12, 72-84. https://doi.org/10.1017/S1431927606060090.
APA BAŞKUT S, DÖLEKÇEKİÇ E, GÜNKAYA G, KAVAS T (2022). An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. , 216 - 229. 10.29109/gujsc.1091233
Chicago BAŞKUT Sinem,DÖLEKÇEKİÇ Emrah,GÜNKAYA Göktuğ,KAVAS Taner An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. (2022): 216 - 229. 10.29109/gujsc.1091233
MLA BAŞKUT Sinem,DÖLEKÇEKİÇ Emrah,GÜNKAYA Göktuğ,KAVAS Taner An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. , 2022, ss.216 - 229. 10.29109/gujsc.1091233
AMA BAŞKUT S,DÖLEKÇEKİÇ E,GÜNKAYA G,KAVAS T An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. . 2022; 216 - 229. 10.29109/gujsc.1091233
Vancouver BAŞKUT S,DÖLEKÇEKİÇ E,GÜNKAYA G,KAVAS T An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. . 2022; 216 - 229. 10.29109/gujsc.1091233
IEEE BAŞKUT S,DÖLEKÇEKİÇ E,GÜNKAYA G,KAVAS T "An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass." , ss.216 - 229, 2022. 10.29109/gujsc.1091233
ISNAD BAŞKUT, Sinem vd. "An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass". (2022), 216-229. https://doi.org/10.29109/gujsc.1091233
APA BAŞKUT S, DÖLEKÇEKİÇ E, GÜNKAYA G, KAVAS T (2022). An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, 10(2), 216 - 229. 10.29109/gujsc.1091233
Chicago BAŞKUT Sinem,DÖLEKÇEKİÇ Emrah,GÜNKAYA Göktuğ,KAVAS Taner An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji 10, no.2 (2022): 216 - 229. 10.29109/gujsc.1091233
MLA BAŞKUT Sinem,DÖLEKÇEKİÇ Emrah,GÜNKAYA Göktuğ,KAVAS Taner An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, vol.10, no.2, 2022, ss.216 - 229. 10.29109/gujsc.1091233
AMA BAŞKUT S,DÖLEKÇEKİÇ E,GÜNKAYA G,KAVAS T An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji. 2022; 10(2): 216 - 229. 10.29109/gujsc.1091233
Vancouver BAŞKUT S,DÖLEKÇEKİÇ E,GÜNKAYA G,KAVAS T An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass. Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji. 2022; 10(2): 216 - 229. 10.29109/gujsc.1091233
IEEE BAŞKUT S,DÖLEKÇEKİÇ E,GÜNKAYA G,KAVAS T "An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass." Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji, 10, ss.216 - 229, 2022. 10.29109/gujsc.1091233
ISNAD BAŞKUT, Sinem vd. "An EBSD Study on Crystallization of CaO-MgO-Al2O3-SiO2 (CMAS) Glass". Gazi Üniversitesi Fen Bilimleri Dergisi Part C: Tasarım ve Teknoloji 10/2 (2022), 216-229. https://doi.org/10.29109/gujsc.1091233