Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]

AHMAD, Mohammad Safi; VENUBABU, Goriparthi; TRIPATHI, Umesh Nath

Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]

Umesh Nath TRIPATHI, (Department, of Chemistry, D.D.U. Gorakhpur Univercity Gorakhpur, India)

Mohammad Safi AHMAD, (School of Studies in Chemistry, Vikram Univercity Ujjain, 456 010, India)

Goriparthi VENUBABU (School of Studies in Chemistry, Vikram Univercity Ujjain, 456 010, India)

Turkish Journal of Chemistry

1 0

Yıl: 2007 Cilt: 31 Sayı: 1 Sayfa Aralığı: 45 - 54 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]

Öz:

Chloro organotin(IV) dipyrazolinates of the type $RSnCl(C_{15}H_{12}N_2OX)_2$[where $C_{15}H_{12}N_2OX$ = 3(2'-Hydroxyphenyl)-5(4-X-phenyl)pyrazoline {where X = H (a); $CH_3$(b); $OCH_3$ (c); Cl (d) and R = Me, $Pr^n$ and Ph}] were synthesised by the reaction of $RSnCl_3$ with sodium salt of pyrazolines in 1:2 molar ratio,in anhydrous benzene. These newly synthesised derivatives were characterised by elemental analysis (C, H, N, Cl and Sn), molecular weight measurement and spectral [IR and multinuclear NMR ($^1H$, $^{13}C$ and $^{119}Sn$)] studies. The bidentate behaviour of the pyrazoline ligands was confirmed by IR, $^1H$ and $^{13}C$ NMR spectral data. An octahedral structure around the tin(IV) atom for $RSnCl(C_{15}H_{12}N_2OX)_2$ is suggested.

Anahtar Kelime:

Konular: Mühendislik, Kimya

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	TRIPATHI U, AHMAD M, VENUBABU G (2007). Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. , 45 - 54.
Chicago	TRIPATHI Umesh Nath,AHMAD Mohammad Safi,VENUBABU Goriparthi Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. (2007): 45 - 54.
MLA	TRIPATHI Umesh Nath,AHMAD Mohammad Safi,VENUBABU Goriparthi Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. , 2007, ss.45 - 54.
AMA	TRIPATHI U,AHMAD M,VENUBABU G Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. . 2007; 45 - 54.
Vancouver	TRIPATHI U,AHMAD M,VENUBABU G Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. . 2007; 45 - 54.
IEEE	TRIPATHI U,AHMAD M,VENUBABU G "Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]." , ss.45 - 54, 2007.
ISNAD	TRIPATHI, Umesh Nath vd. "Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]". (2007), 45-54.

APA	TRIPATHI U, AHMAD M, VENUBABU G (2007). Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. Turkish Journal of Chemistry, 31(1), 45 - 54.
Chicago	TRIPATHI Umesh Nath,AHMAD Mohammad Safi,VENUBABU Goriparthi Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. Turkish Journal of Chemistry 31, no.1 (2007): 45 - 54.
MLA	TRIPATHI Umesh Nath,AHMAD Mohammad Safi,VENUBABU Goriparthi Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. Turkish Journal of Chemistry, vol.31, no.1, 2007, ss.45 - 54.
AMA	TRIPATHI U,AHMAD M,VENUBABU G Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. Turkish Journal of Chemistry. 2007; 31(1): 45 - 54.
Vancouver	TRIPATHI U,AHMAD M,VENUBABU G Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]. Turkish Journal of Chemistry. 2007; 31(1): 45 - 54.
IEEE	TRIPATHI U,AHMAD M,VENUBABU G "Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]." Turkish Journal of Chemistry, 31, ss.45 - 54, 2007.
ISNAD	TRIPATHI, Umesh Nath vd. "Synthesis and spectral characterisation of chloro organotin (IV) di [3(2'-hydroxyphenyl)-5-(4-substituted pheny) pyrazolinates]". Turkish Journal of Chemistry 31/1 (2007), 45-54.