Yıl: 2007 Cilt: 31 Sayı: 5 Sayfa Aralığı: 465 - 471 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Characterization and CO oxidation activity studies of Co-based catalysts

Öz:
Cobalt oxide based catalysts were developed for carbon monoxide oxidation at low temperature. The catalysts were prepared by co-precipitation and calcined at $200 ^circ$ C. Several techniques were used to characterize the catalysts, such as X-ray diffractometer system, $N_2$ physisorption measurements, scanning electron microscope (SEM), and X-ray photoelectron spectroscopy. Carbon monoxide oxidation studies were carried out to investigate the relation between the characteristic properties of the catalysts and the catalytic activity. Catalytic activity measurements were studied from room temperature to $200 ^circ$, using a feed composition of 1% CO, 21% O2, and remaining He. X-ray studies showed that the catalysts have an amorphous phase structure. The average pore diameter of the catalysts was in the mesopore diameter range. The pore sizes and pore volumes of the catalysts increased with increasing molar ratio of cobalt oxide in the catalysts. BET surface areas of the catalysts mostly depend on the cobalt oxide molar ratio in the structure of the catalysts. Low temperature CO oxidation activity measurements showed that the best activity was obtained from the 50/50 $Co_3O_4/CeO_2$ catalyst, which has the light of temperature around $122 ^circ$ and yielded 100% CO conversion above $160 ^circ$.
Anahtar Kelime:

Konular: Mühendislik, Kimya
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA BALIKÇI F, GÜLDÜR F (2007). Characterization and CO oxidation activity studies of Co-based catalysts. , 465 - 471.
Chicago BALIKÇI Filiz,GÜLDÜR FATMA ÇİĞDEM Characterization and CO oxidation activity studies of Co-based catalysts. (2007): 465 - 471.
MLA BALIKÇI Filiz,GÜLDÜR FATMA ÇİĞDEM Characterization and CO oxidation activity studies of Co-based catalysts. , 2007, ss.465 - 471.
AMA BALIKÇI F,GÜLDÜR F Characterization and CO oxidation activity studies of Co-based catalysts. . 2007; 465 - 471.
Vancouver BALIKÇI F,GÜLDÜR F Characterization and CO oxidation activity studies of Co-based catalysts. . 2007; 465 - 471.
IEEE BALIKÇI F,GÜLDÜR F "Characterization and CO oxidation activity studies of Co-based catalysts." , ss.465 - 471, 2007.
ISNAD BALIKÇI, Filiz - GÜLDÜR, FATMA ÇİĞDEM. "Characterization and CO oxidation activity studies of Co-based catalysts". (2007), 465-471.
APA BALIKÇI F, GÜLDÜR F (2007). Characterization and CO oxidation activity studies of Co-based catalysts. Turkish Journal of Chemistry, 31(5), 465 - 471.
Chicago BALIKÇI Filiz,GÜLDÜR FATMA ÇİĞDEM Characterization and CO oxidation activity studies of Co-based catalysts. Turkish Journal of Chemistry 31, no.5 (2007): 465 - 471.
MLA BALIKÇI Filiz,GÜLDÜR FATMA ÇİĞDEM Characterization and CO oxidation activity studies of Co-based catalysts. Turkish Journal of Chemistry, vol.31, no.5, 2007, ss.465 - 471.
AMA BALIKÇI F,GÜLDÜR F Characterization and CO oxidation activity studies of Co-based catalysts. Turkish Journal of Chemistry. 2007; 31(5): 465 - 471.
Vancouver BALIKÇI F,GÜLDÜR F Characterization and CO oxidation activity studies of Co-based catalysts. Turkish Journal of Chemistry. 2007; 31(5): 465 - 471.
IEEE BALIKÇI F,GÜLDÜR F "Characterization and CO oxidation activity studies of Co-based catalysts." Turkish Journal of Chemistry, 31, ss.465 - 471, 2007.
ISNAD BALIKÇI, Filiz - GÜLDÜR, FATMA ÇİĞDEM. "Characterization and CO oxidation activity studies of Co-based catalysts". Turkish Journal of Chemistry 31/5 (2007), 465-471.