Yıl: 2007 Cilt: 31 Sayı: 5 Sayfa Aralığı: 551 - 567 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals

Öz:
In this review article, some of the challenging research areas related to the development of novel catalysts and catalytic processes for the chemical fixation of CO2 by converting it to alcohols and ethers, and for the conversion of alcohols to olefins and other hydrocarbons are reviewed. Ethanol, methanol, and the ethers derived from them, such as DEE and DME, have good burning characteristics and may be considered attractive transportation fuel alternates. New processes for catalytic selective oxidation and dehydration of alcohols may open up new pathways for the production of olefins and other petrochemicals from non-petroleum feedstock. Developments in CO2 capture and its chemical fixation processes will help reduce CO2 emissions into the atmosphere and will produce alternative fuels to petroleum. All these new processes involve challenging catalysis research.
Anahtar Kelime:

Konular: Mühendislik, Kimya
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
  • 1. G.A. Olah, A. Goeppert and G.K.S. Prakash, “Beyond Oil and Gas: The Methanol Economy”, Wiley-VCH Verlag GmbH & Co., 2006.
  • 2. C. Song, Catal. Today, 115, 2-32 (2006).
  • 3. IPCC Working Group http://stephenschneider.stanford.edu/Climate/Climate_Science/ VariationsSurfaceTemperature.html
  • 4. D.M. Etheridge, L.P. Steele, R.L. Langenfelds, R.J. Francey, J.M. Barnola and V.I. Morgan, A Compendium of Data on Global Change, Carbon Dioxide Information Analysis Center, http://cdiac.esd.ornl
  • 5. G.A. Olah, Angew. Chem. Int. Edit. 44, 2636-2639 (2005).
  • 6. F. Ancillotti and V. Fattore, Fuel Process. Technol. 57, 163-194 (1998).
  • 7. G.L. Harting and H. Shannon, in Chemical reactor technology for environmentally safe reactors and products; De Lasa H., Dogu G., Ravella A. Ed.; NATO ASI Ser. Kluwer Acad. Publ. Vol 225, 7-16 (1993)
  • 8. U. Sahapatsombot, (PhD Thesis) http://cuir.car.chula.ac.th/bitstream/123456789/2119/1/Ukrit.pdf
  • 9. J.J. Eberhard, Alternative Fuels in Trucking, 6, 1-7 (1997). http://www.eere.energy.gov/afdc/pdfs/truk6-2.pdf
  • 10. Bioethanol and Blend Properties http://www.visionengineer.com/env/alt_ bioethanol_ prop.shtml
  • 11. N. Oktar, K. Murtezaoglu, G. Dogu G., I. Gonderten and T. Dogu, J. Chem. Technol. Biot. 74, 155-161 (1999).
  • 12. J. Linnekoski and A.O. Krause, Ind. Eng. Chem. Res. 36, 310-316 (1997).
  • 13. D. Varisli and T. Dogu, Ind. Eng. Chem. Res. 44, 5227-5232 (2005).
  • 14. N. Boz and T. Dogu, AIChE J., 51,631-640 (2005).
  • 15. Diethyl ether-Wikipedia, the free encyclopedia http://en.wikipedia.org/wiki/Diethyl ether
  • 16. J.J. Eberhardt, J.J., Alternate Fuels, 6(2), 1-7 (1997). http://www.eere.energy.gov/afdc/pdfs/truk6-2.pdf
  • 17. Japan DME Forum (http://www.dmeforum.jp/about/index_ e.html)
  • 18. DME Properties ( http://www.visionengineer.com/env/alt_ dme_ prop.shtml )
  • 19. G.J. Suppes, J.G. Terry, M.L. Burkhart and M.P. Cupps, Ind. Eng. Chem. Res., 37, 2029-2038 (1998).
  • 20. J. Song, Z. Huang, X., Qiao and W. Wang, Energ. Convers. Manage. 45, 2223-2232 (2004).
  • 21. R. Shinnar, Chem. Eng. Prog. 5-6, Nov. (2004). www.cepmagazin.org November 2004.
  • 22. M. Ni, M.K.H. Leung, D.Y.C. Leung and K. Sumathy, Renewable and Sustainable Energy Reviews, 11, 401-425 (2007).
  • 23. C.J. Xing, Y.J. Zhang, W. Yan and L.J. Guo, Int. J. Hydrogen Energ. 31, 2018-2024 (2006).
  • 24. G.A. Deluga, J.R. Salge, L.D. Schmidt and X.E. Verykios, Science 303, Issue 5660, 993-997 (2004).
  • 25. J.H. Lee, S.J. Schmieg and S.H. Oh, Ind. Eng. Chem. Res. 43, 6343-6348 (2004).
  • 26. S. Duan, S. Senkan, Ind. Eng. Chem. Res. 44, 6381-6386 (2005).
  • 27. C. Yang, Z. Ma, N. Zhao, W. Wei, T. Hu and Y. Sun, Catal. Today 115, 222-227 (2006).
  • 28. Y. Zhang, J. Fei, Y. Yu and X. Zheng, Energ. Convers. Manage. 47, 3360-3367 (2006).
  • 29. J. Sloczynski ,R. Grabowski ,P. Olszewski , A. Kozlowska, J. Stoch, M. Lachowska and J. Skrzypek, Appl. Catal. A-Gen. 310, 127-137 (2006).
  • 30. J. Sloczynski ,R. Grabowski ,A. Kozlowska, P. Olszewski , J. Stoch, J. Skrzypek and M. Lachowska, Appl. Catal. A-Gen. 278, 11-23 (2004).
  • 31. N. Iwasa, H. Suzuki, M. Terashita, M. Arai and N. Takezawa, Catal. Lett. 96, 75-78 (2004).
  • 32. Y. Izumi, H., Kurakata and K. Aika, J. Catal. 175, 236-244 (1998).
  • 33. T. Inuiand T. Yamamoto, Catal. Today 45, 209-214 (1998).
  • 34. T. Inui, T. Yamamoto, M. Inoue, H. Hara, T. Takeguchi and J.B. Kim, Appl. Catal. A-Gen. 186, 395-406 (1999).
  • 35. K. Okabe, H. Yamada, T. Hanaoka, T. Matsuzaki, H. Arakawa and Y. Abe, Chem. Lett. 9, 904-905 (2001).
  • 36. M. Takagawa, A. Okamoto, H. Fuji mura, Y. Izawa and H. Arakawa, Stud. Surf. Sci. Catal. 114, 525-528 (1998).
  • 37. J. Erena, R. Garona, J. M. Arandes, A.T. Aguayo and J. Bilbao, Catal. Today 107-108, 467-473 (2005).
  • 38. D.S. Mao, W.M. Yang, J.C. Xia, B. Zhang and G.Z Lu, J. Mol. Catal. A-Chem. 250, 138-144 (2006).
  • 39. G. Jia, Yi Tan and Y. Han, Ind. Eng. Chem. Res., 45, 1152-1159 (2006).
  • 40. M.A. Pacheco and C.L. Marshall, Energ. Fuel. 11, 2-29 (1997).
  • 41. K.W. La and I.K. Song, Reac. Kinet. Catal. L. 89, 303-309 (2006).
  • 42. Y. Yoshida, Y. Arai, S. Kado, K. Kunimori and K. Tomishige, Catal. Today 115, 95-101 (2006).
  • 43. M. Aresta, A. Dibenedetto, C. Pastore, I. Papai and G. Schubert, Top. Catal. 40, 71-81 (2006).
  • 44. J.S. Tian, J.Q. Wang, J. Y. Chen, J.G. Fan, F. Cai and L.N. He, Appl. Catal. A- Gen. 301, 215-221 (2006).
  • 45. K. Iwakabe, M. Nakaiwa, T. Sakakura, J.C. Choi, H. Yasuda, T. Takahashi and Y. Ooshima, J. Chem. Eng. Jpn. 38, 1020-1024 (2005).
  • 46. G. Karakas, T. Dogu and T.G. Somer, Ind. Eng. Chem. Res. 36, 4445-4451 (1997).
  • 47. B. Balasubramanian, A.L. Ortiz, S. Kaytakoglu and D.P. Harrison, Chem. Eng. Sci. 54, 3543 (1999).
  • 48. B. Ficicilar, T. Dogu, Catal. Today 115, 274-278 (2006).
  • 49. Z. Yong and A.E. Rodrigues, Energ. Convers. Manage. 43, 1865 (2002).
  • 50. Y. Ding and E. Alpay, Chem. Eng. Sci. 55, 3461 (2000).
  • 51. Z. Yong, V. Mata and A.E. Rodrigues, Sep. Purif. Technol. 26, 195 (2002).
  • 52. R. Tesser, V. Maradei, M.Di Serio and E. Santacesaria, Ind. Eng. Chem. Res. 43, 1623-1633 (2004).
  • 53. T. Feng and J.M. Vohs, J. Phys. Chem. B 109, 2120-2127 (2005).
  • 54. M.F. Gomez, L.A. Arrua, and M.C. Abello, Ind. Eng. Chem. Res. 36, 3468-3472 (1997).
  • 55. E. Santacesaria, A. Sorrentino, R. Tesser, M. Di Serio and A. Ruggiero, J. Mol. Catal. A-Chem. 204-205, 617-627 (2003).
  • 56. N.E. Quaranta, J. Soria, V.C. Corberan and J.L. Fierro, J. Catal. 171, 1-13 (1997).
  • 57. Y. Gucbilmez, T. Dogu and S. Balci, Ind. Eng. Chem. Res., 45, 3496-3502 (2006).
  • 58. Y. Gucbilmez, T. Dogu and S. Balci, Catal. Today, 100, 473-476 (2005).
  • 59. S. Canan, T. Dogu and G. Dogu, Micropor. Mesopor. Mat. 94, 89-98 (2006).
  • 60. S. Velu, L. Wang, M. Okazaki, K. Suzuki and S. Tomura, Microp. Mesop. Mat. 54, 113-126 (2002).
  • 61. C. Hess, I.J. Drake, J.D. Hoefelmeyer, T.D. Tilley and A.T. Bell, Catal. Lett. 105, 1-8 (2005).
  • 62. Y. Yang, G. Du, S. Lim, G.L. Haller, J. Catal. 234, 318-327 (2005).
  • 63. M. Stocker, Microp. Mesop. Mat. 29, 3-48 (1999).
  • 64. F.J. Keil, Microp. Mesop. Mat. 29, 49-66 (1999).
  • 65. G.J. Hutchings, G.W. Watson and D.J. Willcok, Microp. Mesop. Mat. 29, 67-77 (1999).
  • 66. O. Mikkelsen and S. Kolboe, Microp. Mesop. Mat. 29, 173-184 (1999).
  • 67. I.M. Dahl, H. Mostad, D. Akporiaye and R. Wendelbo, Microp. Mesop. Mat. 29, 185-190 (1999).
  • 68. De Chen, K. Moljord, T. Fuglerud and A. Holmen, Microp. Mesop Mat. 29, 191-203 (1999).
  • 69. S.M. Alwahabiand G.F. Froment, Ind. Eng. Chem. Res. 43, 5098-5111 (2004).
  • 70. A.T. Aguayo, A.G. Gayubo, R. Vivanco, A. Alonso and J. Bilbao, Ind. Eng. Chem. Res. 44, 7279-7286 (2005).
  • 71. W. Wang, Y. Yijiao and M. Hunger, Catal. Today 113, 102-114 (2006).
  • 72. J.Q. Chen, A. Bozzano, B. Glover, T. Furglerud and S. Kvisle, Catal. Today 106, 103-107 (2005).
  • 73. A.T. Aguayo, A.G. Gayubo, A.A.M. Olazar and J. Bilbao, Ind. Eng. Chem. Res., 41, 4216-4224 (2002).
  • 74. A.G. Gayubo, A.M. Tarrio, A.T. Aguayo, M. Olazar and J. Bilbao, Ind. Eng. Chem. Res. 40, 3467-3474 (2001).
  • 75. I.M. Dahl, R. Wendelbo, A. Andersen, D. Akporiaye, H. Mostad and T. Fuglerud, Microp. Mesop. Mat. 29, 159-171 (1999).
  • 76. V. Vishwanathan, K.W. Jun, J.W. Kim and H.S. Roh, Appl. Catal. A-Gen. 276, 251-255 (2004).
  • 77. S. Damyanova, M.L. Cubeiro and J.L.G. Fierro, J. Mol.Catal. A-Chem. 142, 85-100 (1999).
  • 78. J.I. Yang, D.W. Lee, J.H. Lee, J.C. Hyun and K.Y. Lee, Appl. Catal. A-Gen. 194-195, 123-127 (2000).
  • 79. D. Varisli, T. Dogu and G. Dogu, Chem. Eng. Sci. in press (2007).
  • 80. J. Haber, K. Pamin, L. Matachowski, B. Napruszewska and J. Poltowicz, J. Catal. 207, 296-306 (2002).
  • 81. S. Kannan, T. Sen and S. Sivasanker, J. Catal., 170, 304-310 (1997).
  • 82. S. Golay, L. Kiwi-Minsker, R. Doepper and A. Renken, Chem. Eng. Sci. 54, 3593-3598 (1999).
  • 83. F.C. Marin, A. Mueden and C.M. Castilla, J. Phys. Chem. B 102, 9239-9244 (1998).
  • 84. J.A. Linnekoski, A.O. Krause and L.K. Rihko, Ind. Eng. Chem. Res. 36, 310-316 (1997).
  • 85. P. Kitchaiya and R. Datta, Ind. Eng. Chem. Res. 34, 1092-1101 (1995).
  • 86. N. Boz, T. Dogu, K. Murtezaoglu and G. Dogu, Appl. Catal. A-Gen. 268, 175-182 (2004).
  • 87. N. Oktar, K. Murtezaoglu, T. Dogu and G. Dogu, Can. J. Chem. Eng. 77, 406 (1999).
  • 88. T. Dogu, E. Aydin, N. Boz, K. Murtezaoglu and G. Dogu, Int. J. Chem. Reactor Eng. 1, A6 (2003).
  • 89. L.K. Rihko, P.K.K. Paakkonen and A.O.I. Krause, Ind. Eng. Chem. Res. 36, 614-621 (1997).
  • 90. P.K. Paakkonen, L. Struckman and A.O.I. Krause, Chem. Eng. Technol. 21, 321-326 (1998).
  • 91. N. Boz, T. Dogu, K. Murtezaoglu and G. Dogu, Catal. Today 100, 419-424 (2005).
  • 92. T. Dogu, N. Boz, E. Aydin, N. Oktar, K. Murtezaoglu and G. Dogu, Ind. Eng. Chem. Res. 40, 5044-5048 (2001).
APA DOĞU T, Varisli D (2007). Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. , 551 - 567.
Chicago DOĞU Timur,Varisli Dilek Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. (2007): 551 - 567.
MLA DOĞU Timur,Varisli Dilek Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. , 2007, ss.551 - 567.
AMA DOĞU T,Varisli D Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. . 2007; 551 - 567.
Vancouver DOĞU T,Varisli D Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. . 2007; 551 - 567.
IEEE DOĞU T,Varisli D "Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals." , ss.551 - 567, 2007.
ISNAD DOĞU, Timur - Varisli, Dilek. "Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals". (2007), 551-567.
APA DOĞU T, Varisli D (2007). Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. Turkish Journal of Chemistry, 31(5), 551 - 567.
Chicago DOĞU Timur,Varisli Dilek Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. Turkish Journal of Chemistry 31, no.5 (2007): 551 - 567.
MLA DOĞU Timur,Varisli Dilek Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. Turkish Journal of Chemistry, vol.31, no.5, 2007, ss.551 - 567.
AMA DOĞU T,Varisli D Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. Turkish Journal of Chemistry. 2007; 31(5): 551 - 567.
Vancouver DOĞU T,Varisli D Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals. Turkish Journal of Chemistry. 2007; 31(5): 551 - 567.
IEEE DOĞU T,Varisli D "Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals." Turkish Journal of Chemistry, 31, ss.551 - 567, 2007.
ISNAD DOĞU, Timur - Varisli, Dilek. "Alcohols as alternatives to petroleum for environmentally clean fuels and petrochemicals". Turkish Journal of Chemistry 31/5 (2007), 551-567.