New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties

Khalil FAGHIHI (Department, of Chemistry, Fac. of Science, Arak Univercity, Arak, 38156, Iran)
Turkish Journal of Chemistry
1 0
Yıl: 2008 Cilt: 32 Sayı: 6 Sayfa Aralığı: 663 - 671 Metin Dili: İngilizce İndeks Tarihi: 29-07-2022

New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties

Öz:
Six new flame-retardant poly(ester-imide)s (9a-f) with high inherent viscosity and containing phosphine oxide moieties in the main chain were synthesized from the polycondensation reaction of N,N-(3,3-diphenylphenyl phosphine oxide) bistrimellitimide diacid chloride (7) with 6 aromatic diols (8a-f) by 2 different methodsr-solution and microwave-assisted polycondensation. The results showed that compared to solution polycondensation, the microwave-assisted polycondensation reaction using a domestic microwave oven proceeded rapidly and was completed within about 9-12 min. All of the obtained polymers were fully characterized by means of elemental analysis, viscosity measurement, solubility testing, and FT-IR spectroscopy. Thermal properties and flame retardant behavior of the PEIs (9a-f) were investigated by using thermal gravimetric analysis (TGA and DTG) and the limited oxygen index (LOI). Data obtained by thermal analysis (TGA and DTG) revealed that these poly(ester-imide)s had good thermal stability. Furthermore, high char yields in TGA and good LOI values indicated that incorporating phosphine oxide moieties in the polymer backbone markedly improved their flame retardancy. These polymers can be potentially utilized in flame retardant thermoplastic materials.
Anahtar Kelime:

Konular: Mühendislik, Kimya
Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA FAGHIHI K (2008). New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. , 663 - 671.
Chicago FAGHIHI Khalil New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. (2008): 663 - 671.
MLA FAGHIHI Khalil New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. , 2008, ss.663 - 671.
AMA FAGHIHI K New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. . 2008; 663 - 671.
Vancouver FAGHIHI K New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. . 2008; 663 - 671.
IEEE FAGHIHI K "New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties." , ss.663 - 671, 2008.
ISNAD FAGHIHI, Khalil. "New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties". (2008), 663-671.
APA FAGHIHI K (2008). New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. Turkish Journal of Chemistry, 32(6), 663 - 671.
Chicago FAGHIHI Khalil New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. Turkish Journal of Chemistry 32, no.6 (2008): 663 - 671.
MLA FAGHIHI Khalil New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. Turkish Journal of Chemistry, vol.32, no.6, 2008, ss.663 - 671.
AMA FAGHIHI K New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. Turkish Journal of Chemistry. 2008; 32(6): 663 - 671.
Vancouver FAGHIHI K New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties. Turkish Journal of Chemistry. 2008; 32(6): 663 - 671.
IEEE FAGHIHI K "New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties." Turkish Journal of Chemistry, 32, ss.663 - 671, 2008.
ISNAD FAGHIHI, Khalil. "New flame-retardant poly(ester-imide)s containing phosphine oxide moieties in the main chain: Synthesis and properties". Turkish Journal of Chemistry 32/6 (2008), 663-671.
Sayfa Oluşturulma Tarihi
22-04-2024 13:42

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