Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts
Yıl: 2023 Cilt: 47 Sayı: 1 Sayfa Aralığı: 116 - 125 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3522 İndeks Tarihi: 13-03-2023
Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts
Öz: In this study, effects of TiO2 and ZnO nanometal oxides on cellulose pyrolysis have been investigated. Both catalysts have been synthesized via hydrothermal method and characterized by using different techniques. Catalytic and catalyst-free experiments were carried out so as to identify the catalytic abilities of synthesized nanoparticles. Catalyst-free experiments were carried out at 500, 600, and 700 °C in order to determine the optimal condition for pyrolysis and it was found as 700 °C. Optimum catalyst ratio for cellulose pyrolysis was found as 5% (w/w) for both TiO2 and ZnO catalysts. GC-MS and micro-GC analyses were conducted in order to examine the catalytic properties of synthesized nanoparticles and illuminate the content of pyrolytic oil and gaseous products. Results showed that maximum gas yield was observed at 700 °C in the presence of 5% $TiO_2$. Maximum activity for both catalysts was observed at 700 °C and the char yield was significantly decreased in each catalytic experiment at specified temperatures, compared to catalyst-free experiments. Both nanoparticles catalyzed the dehydration and decarbonylation reactions and significantly increased the amount of furan derivatives, especially furanic aldehydes.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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| APA | donar y, Unalan A, Ergenekon S, Sınağ A (2023). Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. , 116 - 125. 10.55730/1300-0527.3522 |
| Chicago | donar yusuf osman,Unalan Ali,Ergenekon Samed,Sınağ Ali Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. (2023): 116 - 125. 10.55730/1300-0527.3522 |
| MLA | donar yusuf osman,Unalan Ali,Ergenekon Samed,Sınağ Ali Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. , 2023, ss.116 - 125. 10.55730/1300-0527.3522 |
| AMA | donar y,Unalan A,Ergenekon S,Sınağ A Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. . 2023; 116 - 125. 10.55730/1300-0527.3522 |
| Vancouver | donar y,Unalan A,Ergenekon S,Sınağ A Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. . 2023; 116 - 125. 10.55730/1300-0527.3522 |
| IEEE | donar y,Unalan A,Ergenekon S,Sınağ A "Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts." , ss.116 - 125, 2023. 10.55730/1300-0527.3522 |
| ISNAD | donar, yusuf osman vd. "Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts". (2023), 116-125. https://doi.org/10.55730/1300-0527.3522 |
| APA | donar y, Unalan A, Ergenekon S, Sınağ A (2023). Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. Turkish Journal of Chemistry, 47(1), 116 - 125. 10.55730/1300-0527.3522 |
| Chicago | donar yusuf osman,Unalan Ali,Ergenekon Samed,Sınağ Ali Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. Turkish Journal of Chemistry 47, no.1 (2023): 116 - 125. 10.55730/1300-0527.3522 |
| MLA | donar yusuf osman,Unalan Ali,Ergenekon Samed,Sınağ Ali Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. Turkish Journal of Chemistry, vol.47, no.1, 2023, ss.116 - 125. 10.55730/1300-0527.3522 |
| AMA | donar y,Unalan A,Ergenekon S,Sınağ A Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. Turkish Journal of Chemistry. 2023; 47(1): 116 - 125. 10.55730/1300-0527.3522 |
| Vancouver | donar y,Unalan A,Ergenekon S,Sınağ A Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts. Turkish Journal of Chemistry. 2023; 47(1): 116 - 125. 10.55730/1300-0527.3522 |
| IEEE | donar y,Unalan A,Ergenekon S,Sınağ A "Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts." Turkish Journal of Chemistry, 47, ss.116 - 125, 2023. 10.55730/1300-0527.3522 |
| ISNAD | donar, yusuf osman vd. "Catalytic evaluation of cellulose pyrolysis by using nanosized metal oxide catalysts". Turkish Journal of Chemistry 47/1 (2023), 116-125. https://doi.org/10.55730/1300-0527.3522 |
