Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones

EGLENCE-BAKIR, Songul

doi:10.3906/kim-2101-12

Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones

Songül EĞLENCE BAKIR (İstanbul Üniversitesi, Fen Fakültesi, Kimya Bölümü, İstanbul, Türkiye)

Turkish Journal of Chemistry

4 0

Yıl: 2021 Cilt: 45 Sayı: 3 Sayfa Aralığı: 835 - 844 Metin Dili: İngilizce DOI: 10.3906/kim-2101-12 İndeks Tarihi: 29-06-2022

Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones

Öz:

Six nickel(II) complexes of the $N_2 O_2$ chelating thiosemicarbazones were synthesized using $N^1 -4-$benzyloxysalicylidene-Smethyl/propyl thiosemicarbazone and methoxy-substitute-salicylaldehydes in the presence of Ni(II) ion by template reaction. The structures of thiosemicarbazones and nickel(II) complexes were characterized by elemental analysis, UV-Vis, IR, and 1 H-NMR spectroscopies. The structure of the $N^1 -4-$benzyloxysalicylidene-S-propyl thiosemicarbazone (2) was determined by X-ray single-crystal diffraction method. The total antioxidant capacities of synthesized compounds were evaluated by using cupric reducing antioxidant capacity (CUPRAC) method. The thiosemicarbazones exhibited more potent antioxidant capacity than Ni(II) complexes. Trolox equivalent antioxidant capacity (TEAC) of 1c was found highest in tested nickel(II) complexes. In addition, antioxidant activities of tested compounds were evaluated by using the hydroxyl radical, DPPH radical, and ABTS radical scavenging abilities of these compounds.

Anahtar Kelime:

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık

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APA	EGLENCE-BAKIR S (2021). Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. , 835 - 844. 10.3906/kim-2101-12
Chicago	EGLENCE-BAKIR Songul Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. (2021): 835 - 844. 10.3906/kim-2101-12
MLA	EGLENCE-BAKIR Songul Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. , 2021, ss.835 - 844. 10.3906/kim-2101-12
AMA	EGLENCE-BAKIR S Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. . 2021; 835 - 844. 10.3906/kim-2101-12
Vancouver	EGLENCE-BAKIR S Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. . 2021; 835 - 844. 10.3906/kim-2101-12
IEEE	EGLENCE-BAKIR S "Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones." , ss.835 - 844, 2021. 10.3906/kim-2101-12
ISNAD	EGLENCE-BAKIR, Songul. "Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones". (2021), 835-844. https://doi.org/10.3906/kim-2101-12

APA	EGLENCE-BAKIR S (2021). Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. Turkish Journal of Chemistry, 45(3), 835 - 844. 10.3906/kim-2101-12
Chicago	EGLENCE-BAKIR Songul Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. Turkish Journal of Chemistry 45, no.3 (2021): 835 - 844. 10.3906/kim-2101-12
MLA	EGLENCE-BAKIR Songul Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. Turkish Journal of Chemistry, vol.45, no.3, 2021, ss.835 - 844. 10.3906/kim-2101-12
AMA	EGLENCE-BAKIR S Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. Turkish Journal of Chemistry. 2021; 45(3): 835 - 844. 10.3906/kim-2101-12
Vancouver	EGLENCE-BAKIR S Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones. Turkish Journal of Chemistry. 2021; 45(3): 835 - 844. 10.3906/kim-2101-12
IEEE	EGLENCE-BAKIR S "Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones." Turkish Journal of Chemistry, 45, ss.835 - 844, 2021. 10.3906/kim-2101-12
ISNAD	EGLENCE-BAKIR, Songul. "Synthesis and antioxidant activities of new nickel(II) complexes derived from 4-benzyloxysalicylidene-S-methyl/propyl thiosemicarbazones". Turkish Journal of Chemistry 45/3 (2021), 835-844. https://doi.org/10.3906/kim-2101-12