Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst
Yıl: 2022 Cilt: 46 Sayı: 6 Sayfa Aralığı: 2102 - 2111 Metin Dili: İngilizce DOI: 10.55730/1300-0527.3506 İndeks Tarihi: 02-01-2023
Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst
Öz: In this study, Pd/C, Cu/C, and a series of PdCu/C bimetallic electrocatalysts were prepared by microwave-assisted modified polyol method to determine glycerol electrooxidation reaction (GOR) activities. The effect of microwave duration on catalyst structure and GOR activity was investigated on PdCu/C bimetallic catalysts. Also, a commercial Pd/C (com-Pd/C) was used to compare catalytic activities with prepared samples. Electrocatalysts were characterized by using X-ray Diffraction (XRD), Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES), and Transmission Electron Microscopy (TEM) analyses. In addition, the activity and stability of electrocatalysts for GOR were examined by using cyclic voltammetry (CV) and chronoamperometry (CA). In XRD results, the formation of PdCu alloy structure was observed successfully in all bimetallic catalysts. It was found that the PdCu electrocatalyst with microwave duration of 150 s (PdCu150) was exhibited homogeneous dispersion in TEM images. The particle size of 6.45 nm for PdCu150 was identified from TEM. Furthermore, the performance results were indicated that PdCu150 has the highest activity (36.02 mA/cm2) and stability compared to Pd/C (8.56 mA/cm2), and com-Pd/C (10.23 mA/cm2) in glycerol electrooxidation.
Anahtar Kelime: Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
- 1. Ashok A, Kumar A. Ag/Co3O4 as an effective catalyst for glycerol electro-oxidation in alkaline medium. International Journal of Hydrogen Energy 2021; 46:4788–4797. https://doi.org/10.1016/j.ijhydene.2020.04.118
- 2. Öztürk O, Haşimoğlu A, Özdemir OK, Karaaslan İ, Ahsen AŞ. Low loaded Pt-Co catalyst surfaces optimized by magnetron sputtering sequential deposition technique for PEM fuel cell applications: physical and electrochemical analysis on carbon paper support. Turkish Journal of Chemistry 2021; 45:1336–1352. https://doi.org/10.3906/kim-2101-50
- 3. Özcan O, Akın AN. Thermodynamic analysis of methanol steam reforming to produce hydrogen for HT-PEMFC: An optimization study. International Journal of Hydrogen Energy 2019; 44:14117–14126. https://doi.org/10.1016/j.ijhydene.2018.12.211
- 4. Chen SS, Yang ZZ, Wang AJ, Fang KM, Feng JJ. Facile synthesis of bimetallic gold-palladium nanocrystals as effective and durable advanced catalysts for improved electrocatalytic performances of ethylene glycol and glycerol oxidation. Journal of Colloid and Interface Science 2018; 509:10–17. https://doi.org/10.1016/j.jcis.2017.08.063
- 5. Rezaei B, Saeidi-Boroujeni S, Havakeshian E, Ensafi AA. Highly efficient electrocatalytic oxidation of glycerol by Pt-Pd/Cu trimetallic nanostructure electrocatalyst supported on nanoporous stainless steel electrode using galvanic replacement. Electrochimica Acta 2016; 203:41–50. https://doi.org/10.1016/j.electacta.2016.04.024
- 6. Quintero-Pulido DF, Ten-Kortenaar MV, Hurink JL, Smit GJM. A Practical Approach in Glycerol Oxidation for the Development of A Glycerol Fuel Cell. Trends in Green Chemistry 2017; 03:1–17. https://doi.org/10.21767/2471-9889.100018
- 7. Houache MSE, Shubair A, Sandoval MG, Safari R, Botton GA et al. Influence of Pd and Au on electrochemical valorization of glycerol over Ni-rich surfaces. Journal of Catalysis Journal 2021; 396:1–13. https://doi.org/10.1016/j.jcat.2021.02.008
- 8. Zhou Y, Shen Y. Electro-oxidation of glycerol by tetrametallic platinum-gold–palladium-silver nanoparticles. Journal of Applied Electrochemistry 2021; 51:79–86. https://doi.org/10.1007/s10800-020-01426-z
- 9. Maya-Cornejo J, Arjona N, Guerra-Balcázar M, Álvarez-Contreras L, Ledesma-García J et al. Synthesis of Pd-Cu Bimetallic Electrocatalyst for Ethylene Glycol and Glycerol Oxidations in Alkaline Media. Procedia Chemistry 2014; 12:19–26. https://doi.org/10.1016/j. proche.2014.12.036
- 10. Caglar B, El Hassan Y, Basak O, Hepbasli A. Electrooxidation of Glycerol on Monometallic and Bimetallic Catalysts-Containing Porous Carbon Cloth Electrodes in an Alkaline Medium. Journal of the Electrochemical Society 2021; 168:084506. https://doi.org/10.1149/1945- 7111/ac1a57
- 11. Imhanria S, Deng X, Tan T, Deng J, Xu L et al. Phosphating a Pd-rich ‘dealloyed PdCo3 nanoparticles’: An effective electrocatalyst for glycerol oxidation reaction. Journal of Alloys and Compounds 2021; 868:159058. https://doi.org/10.1016/j.jallcom.2021.159058
- 12. Li T, Harrington DA. An Overview of Glycerol Electrooxidation Mechanisms on Pt, Pd and Au. ChemSusChem 2021; 14:1472–1495. https://doi.org/10.1002/cssc.202002669
- 13. Munoz F, Hua C, Kwong T, Tran L, Nguyen TQ et al. Palladium-copper electrocatalyst for the promotion of the electrochemical oxidation of polyalcohol fuels in the alkaline direct alcohol fuel cell. Applied Catalysis B: Environmental 2015; 174–175:323–328. https://doi. org/10.1016/j.apcatb.2015.03.027
- 14. Wang R, Jiang LY, Feng JJ, Liu WD, Yuan J et al. One-pot solvothermal synthesis of PdCu nanocrystals with enhanced electrocatalytic activity toward glycerol oxidation and hydrogen evolution. International Journal of Hydrogen Energy 2017; 42(10):6695-6704. https://doi. org/10.1016/j.ijhydene.2016.12.100
- 15. Liu Z, Lee JY, Chen W, Han M, Gan LM. Physical and Electrochemical Characterizations of Microwave-Assisted Polyol Preparation of Carbon-Supported PtRu Nanoparticles. Langmuir 2004; 20:181–187. https://doi.org/10.1021/la035204i
- 16. Blosi M, Albonetti S, Dondi M, Martelli C, Baldi G. Microwave-assisted polyol synthesis of Cu nanoparticles. Journal of Nanoparticle Research 2011; 13:127–138. https://doi.org/10.1007/s11051-010-0010-7
- 17. Tuval T, Gedanken A. A microwave-assisted polyol method for the deposition of silver nanoparticles on silica spheres. Nanotechnology 2007; 18:255601. https://doi.org/10.1088/0957-4484/18/25/255601
- 18. Demir-Kivrak H. The effect of temperature and concentration for methanol electrooxidation on Pt-Ru catalyst synthesized by microwave assisted route. Turkish Journal of Chemistry 2015; 39:563–575. https://doi.org/10.3906/kim-1411-21
- 19. Duan D, You X, Liang J, Liu S, Wang Y. Carbon supported Cu-Pd nanoparticles as anode catalyst for direct borohydride-hydrogen peroxide fuel cells. Electrochimica Acta 2015; 176:1126–1135. https://doi.org/10.1016/j.electacta.2015.07.118
- 20. Behmenyar G, Akin AN. Investigation of carbon supported Pd-Cu nanoparticles as anode catalysts for direct borohydride fuel cell. Journal of Power Sources 2014; 249:239–246. https://doi.org/10.1016/j.jpowsour.2013.10.063
- 21. Doğan-Özcan M, Akay RG, Çelik C, Akın AN. Preparation and characterization of bimetallic Pd–Zn nanoparticles on carbon for borohydride electrooxidation. Reaction Kinetics, Mechanisms and Catalysis 2021; 134:163– 177. https://doi.org/10.1007/s11144-021- 02056-y
- 22. Lertthahan P, Yongprapat S, Therdthianwong A, Therdthianwong S. Pt-modified Au/C catalysts for direct glycerol electro-oxidation in an alkaline medium. International Journal of Hydrogen Energy 2017; 42:9202–9209. https://doi.org/10.1016/j.ijhydene.2016.05.120
- 23. Bhunia K, Khilari S, Pradhan D. Monodispersed PtPdNi Trimetallic Nanoparticles-Integrated Reduced Graphene Oxide Hybrid Platform for Direct Alcohol Fuel Cell. ACS Sustainable Chemistry & Engineering 2018; 6:7769–7778. https://doi.org/10.1021/acssuschemeng.8b00721
- 24. Li DN, He YM, Feng JJ, Zhang QL, Zhang L et al. Facile synthesis of prickly platinum-palladium core-shell nanocrystals and their boosted electrocatalytic activity towards polyhydric alcohols oxidation and hydrogen evolution. Journal of Colloid and Interface Science 2018; 516:476–483. https://doi.org/10.1016/j.jcis.2018.01.060
- 25. Zhang Z, Xin L, Qi J, Chadderdon DJ, Li W. Supported Pt, Pd and Au nanoparticle anode catalysts for anion-exchange membrane fuel cells with glycerol and crude glycerol fuels. Applied Catalysis B: Environmental 2013; 136–137:29–39. https://doi.org/10.1016/j. apcatb.2013.01.045
- 26. Qi J, Benipal N, Liang C, Li W. PdAg/CNT catalyzed alcohol oxidation reaction for high-performance anion exchange membrane direct alcohol fuel cell (alcohol = methanol, ethanol, ethylene glycol and glycerol). Applied Catalysis B: Environmental 2016; 199:494–503. https://doi.org/10.1016/j.apcatb.2016.06.055
| APA | Ağtoprak K, DOĞAN ÖZCAN M, AKIN A, Akay R (2022). Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. , 2102 - 2111. 10.55730/1300-0527.3506 |
| Chicago | Ağtoprak Kübranur,DOĞAN ÖZCAN Merve,AKIN Ayşe Nilgün,Akay R. Gültekin Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. (2022): 2102 - 2111. 10.55730/1300-0527.3506 |
| MLA | Ağtoprak Kübranur,DOĞAN ÖZCAN Merve,AKIN Ayşe Nilgün,Akay R. Gültekin Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. , 2022, ss.2102 - 2111. 10.55730/1300-0527.3506 |
| AMA | Ağtoprak K,DOĞAN ÖZCAN M,AKIN A,Akay R Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. . 2022; 2102 - 2111. 10.55730/1300-0527.3506 |
| Vancouver | Ağtoprak K,DOĞAN ÖZCAN M,AKIN A,Akay R Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. . 2022; 2102 - 2111. 10.55730/1300-0527.3506 |
| IEEE | Ağtoprak K,DOĞAN ÖZCAN M,AKIN A,Akay R "Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst." , ss.2102 - 2111, 2022. 10.55730/1300-0527.3506 |
| ISNAD | Ağtoprak, Kübranur vd. "Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst". (2022), 2102-2111. https://doi.org/10.55730/1300-0527.3506 |
| APA | Ağtoprak K, DOĞAN ÖZCAN M, AKIN A, Akay R (2022). Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. Turkish Journal of Chemistry, 46(6), 2102 - 2111. 10.55730/1300-0527.3506 |
| Chicago | Ağtoprak Kübranur,DOĞAN ÖZCAN Merve,AKIN Ayşe Nilgün,Akay R. Gültekin Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. Turkish Journal of Chemistry 46, no.6 (2022): 2102 - 2111. 10.55730/1300-0527.3506 |
| MLA | Ağtoprak Kübranur,DOĞAN ÖZCAN Merve,AKIN Ayşe Nilgün,Akay R. Gültekin Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. Turkish Journal of Chemistry, vol.46, no.6, 2022, ss.2102 - 2111. 10.55730/1300-0527.3506 |
| AMA | Ağtoprak K,DOĞAN ÖZCAN M,AKIN A,Akay R Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. Turkish Journal of Chemistry. 2022; 46(6): 2102 - 2111. 10.55730/1300-0527.3506 |
| Vancouver | Ağtoprak K,DOĞAN ÖZCAN M,AKIN A,Akay R Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst. Turkish Journal of Chemistry. 2022; 46(6): 2102 - 2111. 10.55730/1300-0527.3506 |
| IEEE | Ağtoprak K,DOĞAN ÖZCAN M,AKIN A,Akay R "Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst." Turkish Journal of Chemistry, 46, ss.2102 - 2111, 2022. 10.55730/1300-0527.3506 |
| ISNAD | Ağtoprak, Kübranur vd. "Investigation of glycerol electrooxidation activity of carbon supported PdCu bimetallic electrocatalyst". Turkish Journal of Chemistry 46/6 (2022), 2102-2111. https://doi.org/10.55730/1300-0527.3506 |
