Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi

Ayşe KURT, (Bursa Uludağ Üniversitesi, Merkez Araştırma Laboratuvarı, Görükle Kampüsü, Bursa, Türkiye)
Fanar SHAKİR, (Bursa Uludağ Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Görükle Kampüsü, Bursa, Türkiye)
Taner YONAR (Bursa Uludağ Üniversitesi, Mühendislik Fakültesi, Çevre Mühendisliği Bölümü, Görükle Kampüsü, Bursa, Türkiye)
Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi
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Yıl: 2023 Cilt: 38 Sayı: 2 Sayfa Aralığı: 1141 - 1152 Metin Dili: Türkçe DOI: 10.17341/gazimmfd.1011142 İndeks Tarihi: 13-03-2023

Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi

Öz:
Bu çalışmada, ampisilin antibiyotiği içeren atıksuların elektrokimyasal oksidasyonunda yeni nesil Sn/Sb/Ni-Ti anotların uygulanabilirliğinin araştırılması amaçlanmıştır. Elektrolit olarak değerlendirmek üzere sodyum klorür ve potasyum klorür olmak üzere iki farklı tür tuz kullanılmıştır. Ancak, potasyum klorür ile giderim verimleri daha yüksek bulunmuştur. Potasyum klorür ile ampisilin ve kimyasal oksijen ihtiyacının tamamen giderilmesi sırasıyla 5 ve 60 dakika reaksiyon süresi sonunda gerçekleşirken; sodyum klorür ile sırasıyla 5 ve 90 dakika sonra gerçekleşmiştir. Sonuç olarak optimum elektrokimyasal reaksiyon koşulları 750 mg L-1 potasyum klorür ilavesi, pH 8 ve 50 mA cm-2 akım yoğunluğu olarak bulunmuştur. Bu çalışmanın sonucunda, ampisilinin bozunması için yeni nesil Sn/Sb/Ni-Ti anotları ile elektrokimyasal oksidasyon prosesleri, daha az reaksiyon süresi ihtiyacı, tam mineralizasyonun sağlanması ve pH ayarlama adımına ihtiyaç duyulmaması açısından gelecekteki uygulamalar için bu konuda umut verici görünmektedir.
Anahtar Kelime: Elektrokimyasal oksidasyon Sn/Sb/Ti-Ni anot ampisilin giderim

The effect of various parameters on electrochemical removal of ampicillin with Sn/Sb/Ni- Ti anodes

Öz:
In this study, it was investigated the applicability of Sn/Sb/Ni-Ti anodes for electrochemical oxidation of ampicillin in aqueous solutions. Potassium chloride, which is one of the salt types were used as electrolyte, affected the removal efficiencies more positively than sodium chloride. Complete removals of ampicillin and chemical oxygen demand were occured after 5 ve 60 min, respectively with potassium chloride addition; while it was necessary after 5 ve 90 min, respectively with sodium chloride addition. The current density value was found to be 50 mA cm-2, which provides the highest removal efficiencies over 90 minute reaction. In addition, it was seen that it is possible to operate the electrochemical oxidation process more economically, when it was studied at the natural pH value of the aqueous antibiotic solution. According to the results of this study, electrochemical oxidation process with Sn/Sb/Ni-Ti anodes for the degradation of ampicillin is considered quite promising for future applications in terms of less reaction time, full mineralization and no need for an extra pH adjustment step.
Anahtar Kelime: Electrochemical oxidation Sn/Sb/Ti-Ni anode ampicillin removal efficienc

Belge Türü: Makale Makale Türü: Araştırma Makalesi Erişim Türü: Erişime Açık
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APA Kurt A, Shakir F, Yonar T (2023). Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. , 1141 - 1152. 10.17341/gazimmfd.1011142
Chicago Kurt Ayşe,Shakir Fanar,Yonar Taner Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. (2023): 1141 - 1152. 10.17341/gazimmfd.1011142
MLA Kurt Ayşe,Shakir Fanar,Yonar Taner Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. , 2023, ss.1141 - 1152. 10.17341/gazimmfd.1011142
AMA Kurt A,Shakir F,Yonar T Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. . 2023; 1141 - 1152. 10.17341/gazimmfd.1011142
Vancouver Kurt A,Shakir F,Yonar T Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. . 2023; 1141 - 1152. 10.17341/gazimmfd.1011142
IEEE Kurt A,Shakir F,Yonar T "Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi." , ss.1141 - 1152, 2023. 10.17341/gazimmfd.1011142
ISNAD Kurt, Ayşe vd. "Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi". (2023), 1141-1152. https://doi.org/10.17341/gazimmfd.1011142
APA Kurt A, Shakir F, Yonar T (2023). Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38(2), 1141 - 1152. 10.17341/gazimmfd.1011142
Chicago Kurt Ayşe,Shakir Fanar,Yonar Taner Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38, no.2 (2023): 1141 - 1152. 10.17341/gazimmfd.1011142
MLA Kurt Ayşe,Shakir Fanar,Yonar Taner Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, vol.38, no.2, 2023, ss.1141 - 1152. 10.17341/gazimmfd.1011142
AMA Kurt A,Shakir F,Yonar T Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2023; 38(2): 1141 - 1152. 10.17341/gazimmfd.1011142
Vancouver Kurt A,Shakir F,Yonar T Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi. Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi. 2023; 38(2): 1141 - 1152. 10.17341/gazimmfd.1011142
IEEE Kurt A,Shakir F,Yonar T "Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi." Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi, 38, ss.1141 - 1152, 2023. 10.17341/gazimmfd.1011142
ISNAD Kurt, Ayşe vd. "Ampisilinin Sn/Sb/Ni-Ti Anotlarla Elektrokimyasal Olarak Giderimine Çeşitli Parametrelerin Etkisi". Gazi Üniversitesi Mühendislik Mimarlık Fakültesi Dergisi 38/2 (2023), 1141-1152. https://doi.org/10.17341/gazimmfd.1011142
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